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Equations of state for a binary fluid

Let tex2html_wrap_inline4431 be the specific Gibbs potential or "free energy" of the fluid (J/kg), then

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displaymath4435

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Also define the specific enthalpy (J/kg)

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and the specific internal energy (J/kg)

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From (2.1) it follows that

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and from (2.4) and (2.6)

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and from (2.5) and (2.6)

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Let

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displaymath4451

displaymath4453

displaymath4455

displaymath4457

displaymath4459

then the specific volume is

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the specific entropy is

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and the chemical potential is

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Auxiliary definitions give the adiabatic lapse rate (from 2.16) as

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the sound speed (using 2.15 and 2.16) as

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The potential temperature definition is

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where tex2html_wrap_inline4473 is a standard pressure usually taken as one atmosphere, or

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where tex2html_wrap_inline4477 absolute potential temperature. This is the temperature which a sample of fluid would have if brought to reference pressure tex2html_wrap_inline4473 adiabatically and without change of S. Also, tex2html_wrap_inline4483 and tex2html_wrap_inline4485 are the values of tex2html_wrap_inline4487 and tex2html_wrap_inline4489 for P, T, and S taken as tex2html_wrap_inline4473 , tex2html_wrap_inline4499 , S.




next up previous contents
Next: Dry air Up: The Hydrodynamic Problem Previous: Basic hydrodynamic and thermodynamic

Steve Baum
Sun May 19 00:59:05 CDT 1996