next up previous contents
Next: Evaluation of the equations Up: The Fundamental Equations of Previous: A more general form

Gibbs' extension of the Kelvin hypothesis to fluid mixtures

In the case of a fluid mixture, it is obvious that must depend upon the composition as as as and . If we have a single dissolved constituent of mass S per unit mass of fluid, then . In extending the Kelvin hypothesis to a fluid mixture it is natural to suppose that a modified form of Eqs. (V-3) is applicable. The modification is simply

Furthermore, if more than one constituent is present then we may replace S by where the latter symbol represents any of of several constituents . Eq. (V-4) represents the most general form of Kelvin's hypothesis and is free of any restrictions regarding thermal gradients, viscosity or diffusion. It is, in essence, the Gibbs extension of the Kelvin hypothesis and is in itself a more far reaching proposition. Like the Kelvin version, Eqs. (V-4) are more than definitions since it is implied that all known empirical data with regard to any fluid are consistent with these equations.


next up previous contents
Next: Evaluation of the equations Up: The Fundamental Equations of Previous: A more general form

Steve Baum
Mon Dec 1 08:50:29 CST 1997